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Radical Polymerization of Trifluoromethyl-substituted Methyl Methacrylates and Their Application for Use in Pressure-Sensitive Paint
https://jaxa.repo.nii.ac.jp/records/22455
https://jaxa.repo.nii.ac.jp/records/224551505bb56-49fa-4450-a2d6-e78218ac426b
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2015-03-26 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Radical Polymerization of Trifluoromethyl-substituted Methyl Methacrylates and Their Application for Use in Pressure-Sensitive Paint | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | suitable | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | radical polymerization | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | fluoropolymers | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | sensors | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
小幡, 誠
× 小幡, 誠× 安里, 涼× 満尾, 和徳× 廣原, 志保× Obata, Makoto× Asato, Ryo× Mitsuo, Kazunori× Hirohara, Shiho |
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著者所属 | ||||||
山梨大学 | ||||||
著者所属 | ||||||
山梨大学 | ||||||
著者所属 | ||||||
宇宙航空研究開発機構航空本部(JAXA) | ||||||
著者所属 | ||||||
宇部工業高等専門学校 | ||||||
著者所属(英) | ||||||
en | ||||||
University of Yamanashi | ||||||
著者所属(英) | ||||||
en | ||||||
University of Yamanashi | ||||||
著者所属(英) | ||||||
en | ||||||
Institute of Aeronautical Technology, Japan Aerospace Exploration Agency (JAXA) | ||||||
著者所属(英) | ||||||
en | ||||||
Ube National College of Technology | ||||||
出版者(英) | ||||||
出版者 | Wiley Periodicals, Inc. | |||||
書誌情報 |
en : Journal of Polymer Science, Part A: Polymer Chemistry 巻 52, 号 7, p. 963-972, 発行日 2014-04-01 |
|||||
抄録(英) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Three CF3-substituted methyl methacrylates (MMAs), 2,2,2-trifluoroethyl methacrylate (TFEMA), 1,1,1,3,3,3-hexafluoroisopropyl methacrylate (HFIPMA) and nonafluoro-tert-butyl methacrylate (NFTBMA), were polymerized by conventional radical polymerization to give oxygen-permeable polymers for application in pressure-sensitive paint (PSP). The radical copolymerizations of styrene with TFEMA, HFIPMA, or NFTBMA were carried out to examine the effect of CF3 groups on the polymerizability. The e values increased in the order of MMA (0.40) < TFEMA (0.76) < HFIPMA (1.19) < NFTBMA (1.31). The homopolymers of TFEMA, HFIPMA and NFTBMA (PTFEMA, PHFIPMA, and PNFTBM, respectively) were examined as polymers for use in PSP using 5,10,15,20-tetrakis(pentafluorophenyl)porphinato platinum(II) (PtTFPP). The PSP consisting of PNFTBMA and PtTFPP exerted very high pressure sensitivity and very low temperature sensitivity. In the absence of oxygen, the temperature sensitivity decreased in the order of PTFEMA > PHFIPMA > PNFTBMA = PMMA, which corresponds to the order of glass transition temperatures (Tg). However, the activation energies of the overall process of the luminescence quenching by oxygen were found to be 16.8 (PMMA), 13.0 (PTFEMA), 6.8 (PHFIPMA), and 4.3 kJ /mol (PNFTBMA). Therefore, the low temperature sensitivity of PNFTBMA was attributed to its high degree of substitution with CF3 groups and to its relatively high Tg value. | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0887-624X | |||||
ISSNONLINE | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1099-0518 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA1068915X | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11624127 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | http://dx.doi.org/10.1002/pola.27076 | |||||
関連名称 | info:doi/10.1002/pola.27076 | |||||
資料番号 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 資料番号: PA1420001000 |