@techreport{oai:jaxa.repo.nii.ac.jp:00001938,
 author = {大貫, 学 and 吉野, 悟 and 三宅, 淳巳 and 富山, 昇吾 and 羽生, 宏人 and 小森谷, 友絵 and 坂本, 恵一 and Ohnuki, Manabu and Yoshino, Satoru and Miyake, Atsumi and Tomiyama, Shogo and Habu, Hiroto and Komoriya, Tomoe and Sakamoto, Keiichi},
 month = {Mar},
 note = {本研究の目的は，ガス発生剤として1,2,4-トリアゾール-3-オン銅錯体硝酸塩(TOCu)を合成し，熱的特性および初期分解機構の検討からTOCuの反応性に及ぼすCuの影響を検討することである．ガス発生剤としての性能評価は燃焼試験により行った．TOCuは，1,2,4-トリアゾール-3-オン(TO)および硝酸銅(Ⅱ)･3水和物(Cu(NO3)2・3H2O)を用いて合成した．元素分析の結果からTOCuは，Cu2+-bis[(C2H3N3O)(NO3)(-)]･2H2Oとして合成された． TOCuの熱的特性を検討し，発熱量および発熱ピークの鋭さからTOおよびTO/Cu(NO3)2・3H2Oのそれらより反応性が向上されたことがわかった．生成ガス分析からTOCuは，N2，H2O， HNCO， HCN，CO2，CO，NOx ，NH3のガスが生成されることがわかった．TOCuの燃焼特性の検討し，Vieille's の式に従い圧力指数を算出し，0.6451であることがわかった．, In order to obtain a better understanding of the thermal characteristics and combustion characteristics of 1,2,4-triazole-3-one copper complex (TOCu), elemental analysis, infrared spectrometry (IR), X-ray diffraction(XRD), sealed cell-differential scanning calorimetry (SC-DSC), themogravimetry-differential thermal analysis-mass spectrometry (TG-DTA-MS) and burning test were performed. TOCu was synthesized from 1,2,4-triazole-3-one (TO) and trihydrated copper nitrate (Cu(NO3)2･3H2O). TOCu was obtained as 〔Cu(2+)(C2N3H3O)2(NO3)(-)2・2H2O〕. From the DSC results, the heat of reaction of TOCu was larger than those of pure TO and TO/Cu(NO3)2･3H2O mixtures. The exothermic peak of TOCu sharply became compared with those of pure TO and TO/Cu(NO3)2･3H2O mixtures. It was found that the reactivity of TOCu was improved to compared with those of pure TO and TO/Cu(NO3)2･3H2O mixtures. TG-DTA-MS curves of TOCu were showed from 3 steps of mass loss, exothermic peak and decomposition gases in the temperature ranges were 100-180 C, 200-260 C and 300-360 C. From the results of TG-DTA-MS, the gases evolved from TOCu were determined as N2, H2O, HNCO, HCN, CO2, CO, NOx and NH3 at 100-360 C. From burning test results, the burning rate of TOCu was calculated by pressure exponent 0.6451 based on Vieille's law., 形態: カラー図版あり, Physical characteristics: Original contains color illustrations, 資料番号: AA1530013005, レポート番号: JAXA-RR-14-005},
 title = {1,2,4-トリアゾール-3-オン銅錯体硝酸塩の熱的特性および燃焼特性},
 year = {2015}
}