{"created":"2023-06-20T14:35:40.384291+00:00","id":1938,"links":{},"metadata":{"_buckets":{"deposit":"50cc1ea3-8f63-4abc-8cbd-c89ec71051f0"},"_deposit":{"created_by":1,"id":"1938","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"1938"},"status":"published"},"_oai":{"id":"oai:jaxa.repo.nii.ac.jp:00001938","sets":["1398:1421:1426","1887:1893","9:10:62:70"]},"author_link":["1621","1617","1614","1619","1618","1615","1616","1609","1611","1608","1620","1610","1613","1612"],"item_3_alternative_title_2":{"attribute_name":"その他のタイトル（英）","attribute_value_mlt":[{"subitem_alternative_title":"Thermal and combustion characteristics of 1,2,4-triazole-3-one copper complex nitrate"}]},"item_3_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-03-13","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"39","bibliographicPageStart":"33","bibliographicVolumeNumber":"JAXA-RR-14-005","bibliographic_titles":[{"bibliographic_title":"宇宙航空研究開発機構研究開発報告: 高エネルギー物質研究会: 平成26年度研究成果報告書"},{"bibliographic_title":"JAXA Research and Development Report","bibliographic_titleLang":"en"}]}]},"item_3_description_16":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究の目的は，ガス発生剤として1,2,4-トリアゾール-3-オン銅錯体硝酸塩(TOCu)を合成し，熱的特性および初期分解機構の検討からTOCuの反応性に及ぼすCuの影響を検討することである．ガス発生剤としての性能評価は燃焼試験により行った．TOCuは，1,2,4-トリアゾール-3-オン(TO)および硝酸銅(Ⅱ)･3水和物(Cu(NO3)2・3H2O)を用いて合成した．元素分析の結果からTOCuは，Cu2+-bis[(C2H3N3O)(NO3)(-)]･2H2Oとして合成された． TOCuの熱的特性を検討し，発熱量および発熱ピークの鋭さからTOおよびTO/Cu(NO3)2・3H2Oのそれらより反応性が向上されたことがわかった．生成ガス分析からTOCuは，N2，H2O， HNCO， HCN，CO2，CO，NOx ，NH3のガスが生成されることがわかった．TOCuの燃焼特性の検討し，Vieille's の式に従い圧力指数を算出し，0.6451であることがわかった．","subitem_description_type":"Abstract"}]},"item_3_description_17":{"attribute_name":"抄録（英）","attribute_value_mlt":[{"subitem_description":"In order to obtain a better understanding of the thermal characteristics and combustion characteristics of 1,2,4-triazole-3-one copper complex (TOCu), elemental analysis, infrared spectrometry (IR), X-ray diffraction(XRD), sealed cell-differential scanning calorimetry (SC-DSC), themogravimetry-differential thermal analysis-mass spectrometry (TG-DTA-MS) and burning test were performed. TOCu was synthesized from 1,2,4-triazole-3-one (TO) and trihydrated copper nitrate (Cu(NO3)2･3H2O). TOCu was obtained as 〔Cu(2+)(C2N3H3O)2(NO3)(-)2・2H2O〕. From the DSC results, the heat of reaction of TOCu was larger than those of pure TO and TO/Cu(NO3)2･3H2O mixtures. The exothermic peak of TOCu sharply became compared with those of pure TO and TO/Cu(NO3)2･3H2O mixtures. It was found that the reactivity of TOCu was improved to compared with those of pure TO and TO/Cu(NO3)2･3H2O mixtures. TG-DTA-MS curves of TOCu were showed from 3 steps of mass loss, exothermic peak and decomposition gases in the temperature ranges were 100-180 C, 200-260 C and 300-360 C. From the results of TG-DTA-MS, the gases evolved from TOCu were determined as N2, H2O, HNCO, HCN, CO2, CO, NOx and NH3 at 100-360 C. From burning test results, the burning rate of TOCu was calculated by pressure exponent 0.6451 based on Vieille's law.","subitem_description_type":"Other"}]},"item_3_description_18":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"形態: カラー図版あり","subitem_description_type":"Other"}]},"item_3_description_19":{"attribute_name":"内容記述（英）","attribute_value_mlt":[{"subitem_description":"Physical characteristics: Original contains color illustrations","subitem_description_type":"Other"}]},"item_3_description_32":{"attribute_name":"資料番号","attribute_value_mlt":[{"subitem_description":"資料番号: AA1530013005","subitem_description_type":"Other"}]},"item_3_description_33":{"attribute_name":"レポート番号","attribute_value_mlt":[{"subitem_description":"レポート番号: JAXA-RR-14-005","subitem_description_type":"Other"}]},"item_3_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"宇宙航空研究開発機構(JAXA)"}]},"item_3_publisher_9":{"attribute_name":"出版者（英）","attribute_value_mlt":[{"subitem_publisher":"Japan Aerospace Exploration Agency (JAXA)"}]},"item_3_source_id_21":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1349-1113","subitem_source_identifier_type":"ISSN"}]},"item_3_source_id_24":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1192675X","subitem_source_identifier_type":"NCID"}]},"item_3_text_6":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"日本大学"},{"subitem_text_value":"日本大学"},{"subitem_text_value":"横浜国立大学"},{"subitem_text_value":"株式会社ダイセル"},{"subitem_text_value":"宇宙航空研究開発機構宇宙科学研究所宇宙飛翔工学研究系(JAXA)(ISAS)"},{"subitem_text_value":"日本大学"},{"subitem_text_value":"日本大学"}]},"item_3_text_7":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Nihon University"},{"subitem_text_language":"en","subitem_text_value":"Nihon University"},{"subitem_text_language":"en","subitem_text_value":"Yokohama National University"},{"subitem_text_language":"en","subitem_text_value":"Daicel Corporation"},{"subitem_text_language":"en","subitem_text_value":"Department of Space Flight Systems, Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency (JAXA)(ISAS)"},{"subitem_text_language":"en","subitem_text_value":"Nihon University"},{"subitem_text_language":"en","subitem_text_value":"Nihon University"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"大貫, 学"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"吉野, 悟"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"三宅, 淳巳"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"富山, 昇吾"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"羽生, 宏人"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"小森谷, 友絵"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"坂本, 恵一"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ohnuki, Manabu","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yoshino, Satoru","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Miyake, Atsumi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tomiyama, Shogo","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Habu, Hiroto","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Komoriya, Tomoe","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sakamoto, Keiichi","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-15"}],"displaytype":"detail","filename":"AA1530013005.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AA1530013005.pdf","url":"https://jaxa.repo.nii.ac.jp/record/1938/files/AA1530013005.pdf"},"version_id":"cc961267-62cc-4398-b9c3-11b09e4e8f9c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"gas-generating agents","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"1,2,4-triazole-3-one cooper complex","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"combustion characteristics","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"thermal characteristics","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"technical report","resourceuri":"http://purl.org/coar/resource_type/c_18gh"}]},"item_title":"1,2,4-トリアゾール-3-オン銅錯体硝酸塩の熱的特性および燃焼特性","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"1,2,4-トリアゾール-3-オン銅錯体硝酸塩の熱的特性および燃焼特性"}]},"item_type_id":"3","owner":"1","path":["70","1426","1893"],"pubdate":{"attribute_name":"公開日","attribute_value":"2015-04-10"},"publish_date":"2015-04-10","publish_status":"0","recid":"1938","relation_version_is_last":true,"title":["1,2,4-トリアゾール-3-オン銅錯体硝酸塩の熱的特性および燃焼特性"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-06-21T09:31:59.396805+00:00"}