{"created":"2023-06-20T14:54:21.220773+00:00","id":22683,"links":{},"metadata":{"_buckets":{"deposit":"177b758f-2495-48b1-a313-d9bea22267f7"},"_deposit":{"created_by":1,"id":"22683","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"22683"},"status":"published"},"_oai":{"id":"oai:jaxa.repo.nii.ac.jp:00022683","sets":["1887:1888"]},"author_link":["212762","212763","212761","212764","212759","212766","212756","212765","212760","212758","212757","212755"],"item_7_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-05-13","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"28","bibliographicPageEnd":"7667","bibliographicPageStart":"7659","bibliographicVolumeNumber":"119","bibliographic_titles":[{},{"bibliographic_title":"The Journal of Physical Chemistry A","bibliographic_titleLang":"en"}]}]},"item_7_description_17":{"attribute_name":"抄録（英）","attribute_value_mlt":[{"subitem_description":"The reactions of NO2 with cis-/trans-CH3NHNH, CH3NNH2 and CH2NHNH2 have been studied theoretically by quantum chemical calculations and steady-state unimolecular master equation analysis based on RRKM theory. The barrier heights for the roaming transition states between nitro (RNO2) and nitrite (RONO) isomerization reactions and those for the concerted HONO and HNO2 elimination reactions from RNO2 and RONO, affect the pressure dependences of the product-specific rate coefficients. At ambient temperature and pressure, the dominant product of the reactions of NO2 with cis-/trans-CH3NHNH and CH2NHNH2 would be expected to be HONO with trans-CH3NNH and CH2NNH2, respectively, whereas it is CH3N(NH2)NO2 for CH3NNH2 + NO2. The product-specific rate coefficients for the titled and related reactions on the same potential energy surfaces were proposed for kinetics modeling.","subitem_description_type":"Other"}]},"item_7_description_18":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"形態: カラー図版あり","subitem_description_type":"Other"}]},"item_7_description_19":{"attribute_name":"内容記述（英）","attribute_value_mlt":[{"subitem_description":"Physical characteristics: Original contains color illustrations","subitem_description_type":"Other"}]},"item_7_description_32":{"attribute_name":"資料番号","attribute_value_mlt":[{"subitem_description":"資料番号: PA1610065000","subitem_description_type":"Other"}]},"item_7_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"アメリカ化学会"}]},"item_7_publisher_9":{"attribute_name":"出版者（英）","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_7_relation_25":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"info:doi/10.1021/acs.jpca.5b00987"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1021/acs.jpca.5b00987","subitem_relation_type_select":"DOI"}}]},"item_7_source_id_21":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0022-3654","subitem_source_identifier_type":"ISSN"}]},"item_7_source_id_24":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00704789","subitem_source_identifier_type":"NCID"}]},"item_7_text_6":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"名古屋大学"},{"subitem_text_value":"宇宙航空研究開発機構(JAXA)"},{"subitem_text_value":"宇宙航空研究開発機構(JAXA)"},{"subitem_text_value":"東京大学"},{"subitem_text_value":"名古屋大学"},{"subitem_text_value":"横浜国立大学"}]},"item_7_text_7":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Nagoya University"},{"subitem_text_language":"en","subitem_text_value":"Japan Aerospace Exploration Agency (JAXA)"},{"subitem_text_language":"en","subitem_text_value":"Japan Aerospace Exploration Agency (JAXA)"},{"subitem_text_language":"en","subitem_text_value":"The University of Tokyo"},{"subitem_text_language":"en","subitem_text_value":"Nagoya University"},{"subitem_text_language":"en","subitem_text_value":"Yokohama National University"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"metadata only access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_14cb"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"菅野, 望"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"谷, 洋海"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"大門, 優"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"寺島, 洋史"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"吉川, 典彦"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"越, 光男"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kanno, Nozomu","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tani, Hiroumi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Daimon, Yu","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Terashima, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yoshikawa, Norihiko","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Koshi, Mitsuo","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Computational Study of the Rate Coefficients for the Reactions of NO2 with CH3NHNH, CH3NNH2, and CH2NHNH2","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Computational Study of the Rate Coefficients for the Reactions of NO2 with CH3NHNH, CH3NNH2, and CH2NHNH2","subitem_title_language":"en"}]},"item_type_id":"7","owner":"1","path":["1888"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-06-21"},"publish_date":"2016-06-21","publish_status":"0","recid":"22683","relation_version_is_last":true,"title":["Computational Study of the Rate Coefficients for the Reactions of NO2 with CH3NHNH, CH3NNH2, and CH2NHNH2"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-06-21T03:17:05.141904+00:00"}