{"created":"2023-06-20T15:05:21.173385+00:00","id":34651,"links":{},"metadata":{"_buckets":{"deposit":"f2acc4b8-a0e6-4594-a568-acedb75745d2"},"_deposit":{"created_by":1,"id":"34651","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"34651"},"status":"published"},"_oai":{"id":"oai:jaxa.repo.nii.ac.jp:00034651","sets":["1887:1890","1896:1898:1899:1908"]},"author_link":["420065","420064","420063","420062"],"item_9_alternative_title_2":{"attribute_name":"その他のタイトル（英）","attribute_value_mlt":[{"subitem_alternative_title":"Identification of Halogens in Organic Compounds by Means of Paper Chromatography."}]},"item_9_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1951-12-30","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"221","bibliographicPageStart":"217","bibliographicVolumeNumber":"5","bibliographic_titles":[{"bibliographic_title":"東京大學理工學研究所報告"}]}]},"item_9_description_17":{"attribute_name":"抄録（英）","attribute_value_mlt":[{"subitem_description":"Paper chromatograms of sodium halides such as chloride, bromide, and iodide dissolved in water or in aqueous caustic soda of various concentrations, were studied with butanol-picoline, butanol-propanol, or butanol-ammonia as a developing solvent, in order to identify such halides surely by their RF values on chromatograms, and further to apply the result for the identification of halogens contained in organic substances. The spots of halides after development were revealed by their brown coloration of silver sulfide through silver halides. Iodide was rather better identified by means of a characteristic starch method. It was found that butanol-picoline was a suitable solvent to separate spots of the three halides completely, and that these suffered little influence on R_F value or on shape from caustic soda contained in solutions, so far its concentration being within ca. 1.5 N. Sodium cyanide and sulfide. and potassium rhodanate were also chromatographed and found that they located quite separated from halides and gave no disturbance for identification of the latters. On chromatographing a few drops of the decomposition solution with sodium (the alkaline concentration being within the limit quoted above) of various organic substances, which, in addition to halogen, may sometimes contain either nitrogen or sulfur, or both together, halogens contained were identified quite satisfactorily based on the results obtained above. (Received November 17. 1951)","subitem_description_type":"Other"}]},"item_9_description_32":{"attribute_name":"資料番号","attribute_value_mlt":[{"subitem_description":"資料番号: SA2410105000","subitem_description_type":"Other"}]},"item_9_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"東京大学理工学研究所"}]},"item_9_source_id_21":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0371-6090","subitem_source_identifier_type":"ISSN"}]},"item_9_source_id_24":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00162611","subitem_source_identifier_type":"NCID"}]},"item_9_text_6":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"東京大學理工學研究所"},{"subitem_text_value":"東京大學理工學研究所"}]},"item_9_text_7":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"THE INSTITUTE OF SCIENCE AND TECHNOLOGY, UNIVERSITY OF TOKYO"},{"subitem_text_language":"en","subitem_text_value":"THE INSTITUTE OF SCIENCE AND TECHNOLOGY, UNIVERSITY OF TOKYO"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"安藤, 鋭郎"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"石井, 信一"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"ANDO, Toshio","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"ISHII, Shin-ichi","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-01-24"}],"displaytype":"detail","filename":"SA2410105.pdf","filesize":[{"value":"501.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SA2410105.pdf","url":"https://jaxa.repo.nii.ac.jp/record/34651/files/SA2410105.pdf"},"version_id":"d3cf60f0-4231-494d-a71e-a7420b5b18c4"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ペーパークロマトグラフ法による有機化合物中に含まれるハロゲン類の確認","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ペーパークロマトグラフ法による有機化合物中に含まれるハロゲン類の確認"}]},"item_type_id":"9","owner":"1","path":["1890","1908"],"pubdate":{"attribute_name":"公開日","attribute_value":"2015-03-26"},"publish_date":"2015-03-26","publish_status":"0","recid":"34651","relation_version_is_last":true,"title":["ペーパークロマトグラフ法による有機化合物中に含まれるハロゲン類の確認"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-06-20T23:37:43.522509+00:00"}