{"created":"2023-06-20T15:11:26.495961+00:00","id":41096,"links":{},"metadata":{"_buckets":{"deposit":"524ad50e-e73d-4e1e-af32-93ca42906931"},"_deposit":{"created_by":1,"id":"41096","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"41096"},"status":"published"},"_oai":{"id":"oai:jaxa.repo.nii.ac.jp:00041096","sets":["1887:1893","1896:1898:1933:1934"]},"author_link":["501552","501553","501551","501546","501544","501550","501555","501554","501547","501545","501549","501548"],"item_3_alternative_title_2":{"attribute_name":"その他のタイトル（英）","attribute_value_mlt":[{"subitem_alternative_title":"Growth of organic metal crystal under microgravity"}]},"item_3_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1994-10-20","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"951","bibliographicPageStart":"936","bibliographic_titles":[{"bibliographic_title":"宇宙開発事業団技術報告"},{"bibliographic_title":"NASDA Technical Memorandum","bibliographic_titleLang":"en"}]}]},"item_3_description_16":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"良質の大型有機金属結晶を無重力環境下で拡散法を用いて育成する実験について述べた。有機金属として、Tetramethyltetrathiafulvalene(TMTTF)をドナーとし、Tetracyanoquinodimethan(TCNQ)をアクセプタとするTMTTF-TCNQ結晶を選んだ。無重力環境でTMTTFとTCNQをアニソール溶液中で拡散により反応させ、大型セルと小型セルを用いて結晶育成を行った。小型セルではカメラによる結晶育成過程の観察を、大型セルでは物性の測定が可能な結晶を得ることが目的である。実験の結果は次の通り。(1)小型セルにおいて、結晶成長過程の記録は得られなかった。溶液の色は充填時よりも淡くなり、種結晶は完全に消失していた。(2)大型セルにおいて、結晶は全く得られなかった。溶液の色は充填時と殆ど変わらなかった。種結晶の形は充填時と全く同じで、消失していなかった。以上のように、大型および小型セルとも、その中での結晶成長実験は失敗に終った。この失敗の原因調査の一環として、両セルについて溶液の吸収スペクトルの測定を行い、そのスペクトルの解析結果から小型セルについては溶液濃度減少の原因を、また大型セルについてはその不変の原因を考察した。","subitem_description_type":"Abstract"}]},"item_3_description_17":{"attribute_name":"抄録（英）","attribute_value_mlt":[{"subitem_description":"The experiments are conducted to grow high quality large organic metal crystal by means of diffusion method under microgravity. Tetramethyltetrathiafulvalene (TMTTF) - Tetracyanoquinodimethane (TCNQ) crystal in which TMTTF is donor and TCNQ is acceptor was selected as organometal. The crystal growth was made by reacting TMTTF and TCNQ in anisole solution by means of diffusion method in a mini size cell and a big size cell. The aims of the experiments are to observe the process of crystal growth for the mini size cell and to make crystal possible to measure properties of crystal for the big size cell. The results of the experiments are as follows: in the mini size cell, the records on the process of crystal growth were not obtained. Color of the solution became thinner than color at the time of injection, while the seed crystal completely disappeared; and in the big size cell, crystals were not obtained at all. Color of solution did not almost varied compared with color at the time of injection. The shape of seed crystal was entirely same as the shape at the time of injection, and the seed crystal did not appeared. As is above mentioned, the experiments of crystal growth failed both for mini size cell and big size cell. As a part of investigations on causes of the fail, the absorption spectrum of solution was measured for both cells, and from analysis of the spectrum, the cause of decrease of concentration of the solution for the mini size cell and the cause of constancy of concentration of the solution for big size cell were considered.","subitem_description_type":"Other"}]},"item_3_description_32":{"attribute_name":"資料番号","attribute_value_mlt":[{"subitem_description":"資料番号: AA0004116022","subitem_description_type":"Other"}]},"item_3_description_33":{"attribute_name":"レポート番号","attribute_value_mlt":[{"subitem_description":"レポート番号: NASDA-TMR-940002 V.2","subitem_description_type":"Other"}]},"item_3_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"宇宙開発事業団"}]},"item_3_publisher_9":{"attribute_name":"出版者（英）","attribute_value_mlt":[{"subitem_publisher":"National Space Development Agency of Japan (NASDA)"}]},"item_3_source_id_21":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1345-7888","subitem_source_identifier_type":"ISSN"}]},"item_3_source_id_24":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00364784","subitem_source_identifier_type":"NCID"}]},"item_3_text_6":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"姫路工業大学 理学部　物質科学科"},{"subitem_text_value":"姫路工業大学 理学部　物質科学科"},{"subitem_text_value":"石川島播磨重工業 宇宙利用開発部"},{"subitem_text_value":"石川島播磨重工業 宇宙利用開発部"},{"subitem_text_value":"石川島播磨重工業 宇宙利用開発部"},{"subitem_text_value":"宇宙開発事業団 宇宙実験グループ"}]},"item_3_text_7":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Himeji Institute of Technology Department of Materials Science, Faculty of Science"},{"subitem_text_language":"en","subitem_text_value":"Himeji Institute of Technology Department of Materials Science, Faculty of Science"},{"subitem_text_language":"en","subitem_text_value":"Ishikawajima-Harima Heavy Industries Co Space Experiment System Development Department"},{"subitem_text_language":"en","subitem_text_value":"Ishikawajima-Harima Heavy Industries Co Space Experiment System Development Department"},{"subitem_text_language":"en","subitem_text_value":"Ishikawajima-Harima Heavy Industries Co Space Experiment System Development Department"},{"subitem_text_language":"en","subitem_text_value":"NASDA Space Experiment Group"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"安西, 弘行"}],"nameIdentifiers":[{"nameIdentifier":"501544","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"中辻, 慎一"}],"nameIdentifiers":[{"nameIdentifier":"501545","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"長木, 英司"}],"nameIdentifiers":[{"nameIdentifier":"501546","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"荒井, 義人"}],"nameIdentifiers":[{"nameIdentifier":"501547","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"阿野, 良彬"}],"nameIdentifiers":[{"nameIdentifier":"501548","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"上林, 明夫"}],"nameIdentifiers":[{"nameIdentifier":"501549","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Anzai, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"501550","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakatsuji, Shinichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"501551","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nagaki, Eiji","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"501552","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Arai, Yoshito","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"501553","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ano, Yoshiaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"501554","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kanbayashi, Akio","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"501555","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-02-10"}],"displaytype":"detail","filename":"04116022.pdf","filesize":[{"value":"353.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"04116022.pdf","url":"https://jaxa.repo.nii.ac.jp/record/41096/files/04116022.pdf"},"version_id":"83c27a65-4e03-446e-a5c0-716368eff338"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"微小重力","subitem_subject_scheme":"Other"},{"subitem_subject":"有機金属結晶","subitem_subject_scheme":"Other"},{"subitem_subject":"結晶成長","subitem_subject_scheme":"Other"},{"subitem_subject":"拡散法","subitem_subject_scheme":"Other"},{"subitem_subject":"TMTTF-TCNQ結晶","subitem_subject_scheme":"Other"},{"subitem_subject":"テトラメチルテトラチアフルバレン-テトラシアノキノジメタン結晶","subitem_subject_scheme":"Other"},{"subitem_subject":"吸収スペクトル","subitem_subject_scheme":"Other"},{"subitem_subject":"スペクトル測定","subitem_subject_scheme":"Other"},{"subitem_subject":"スペクトル解析","subitem_subject_scheme":"Other"},{"subitem_subject":"大型セル","subitem_subject_scheme":"Other"},{"subitem_subject":"小型セル","subitem_subject_scheme":"Other"},{"subitem_subject":"microgravity","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"organometallic crystal","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"crystal growth","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"diffusion method","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"TMTTF TCNQ crystal","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"tetramethyltetratiafulvalene tetracyanoquinodimethan crystal","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"absorption spectrum","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"spectroscopy","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"spectrum analysis","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"big size cell","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"mini size cell","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"technical report","resourceuri":"http://purl.org/coar/resource_type/c_18gh"}]},"item_title":"無重力環境下における有機金属結晶の成長","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"無重力環境下における有機金属結晶の成長"}]},"item_type_id":"3","owner":"1","path":["1893","1934"],"pubdate":{"attribute_name":"公開日","attribute_value":"2015-03-26"},"publish_date":"2015-03-26","publish_status":"0","recid":"41096","relation_version_is_last":true,"title":["無重力環境下における有機金属結晶の成長"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-06-20T20:26:50.601300+00:00"}