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1,2-ヂクロルエタン溶液の赤外線吸收
https://jaxa.repo.nii.ac.jp/records/33453
https://jaxa.repo.nii.ac.jp/records/334530b3ae988-2ff7-4d86-a85d-9d854eaa5342
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SA0700647.pdf (311.6 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2015-03-26 | |||||||||
| タイトル | ||||||||||
| タイトル | 1,2-ヂクロルエタン溶液の赤外線吸收 | |||||||||
| 言語 | ||||||||||
| 言語 | jpn | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | departmental bulletin paper | |||||||||
| その他のタイトル（英） | ||||||||||
| その他のタイトル | Infrared Spectrum of 1,2-Dichloroethane | |||||||||
| 著者 |
倉谷, 健治
× 倉谷, 健治
× KURATANI, Kenji
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| 著者所属 | ||||||||||
| 東京大學理工學研究所 | ||||||||||
| 著者所属（英） | ||||||||||
| en | ||||||||||
| THE INSTITUTE OF SCIENCE AND TECHNOLOGY, UNIVERSITY OF TOKYO | ||||||||||
| 出版者 | ||||||||||
| 出版者 | 東京大学理工学研究所 | |||||||||
| 書誌情報 |
東京大學理工學研究所報告 巻 6, 号 4, p. 221-224, 発行日 1952-08-20 |
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| 抄録（英） | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | Infrared spectra of dichloroethane in various solvents were obtained with a Baird Infrared Spectrophotometer. Following conclusions were derived : 1. The positions of absorption bands of dichloroethane in benzene solution are not different from those in CCl_4, CS_2, and CH_3CN solutions. Therefore, the complex compound is not formed between the molecules of dichloroethane and benzene. 2. Assuming the energy difference between the trans and gauche forms of dichloroethane in the liquid state, the energy difference between the two forms in various solvents was determined from the intensity ratio of 1284 and 1230 cm^<-1>, or 1430 and 1451 cm^<-1>. 3. Mixed ratio between the two forms in the non-polar solvents does not change with the concentration of dichloroethane. This conclusion is contrary to the association theory presented by Bishui. 4. Infrared band at 1312 cm^<-1> should be assigned to gauche form. (Received July 19, 1952) | |||||||||
| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 0371-6090 | |||||||||
| 書誌レコードID | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| 収録物識別子 | AN00162611 | |||||||||
| 資料番号 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | 資料番号: SA0700647000 | |||||||||
