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Rotational Transitions in Para-Hydrogen by Molecular Collisions
https://jaxa.repo.nii.ac.jp/records/34449
https://jaxa.repo.nii.ac.jp/records/344491049485a-2051-4f60-b18f-7154a7d5579d
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SA2400827.pdf (875.5 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||||
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| 公開日 | 2015-03-26 | |||||||||
| タイトル | ||||||||||
| タイトル | Rotational Transitions in Para-Hydrogen by Molecular Collisions | |||||||||
| 言語 | en | |||||||||
| 言語 | ||||||||||
| 言語 | eng | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | departmental bulletin paper | |||||||||
| 著者 |
SHIMAMURA, Hisako
× SHIMAMURA, Hisako
× TAKAYANAGI, Kazuo
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| 出版者 | ||||||||||
| 出版者 | 東京大学宇宙航空研究所 | |||||||||
| 出版者（英） | ||||||||||
| 出版者 | Institute of Space and Aeronautical Science,University of Tokyo | |||||||||
| 書誌情報 |
en : ISAS report/Institute of Space and Aeronautical Science,University of Tokyo 巻 36, 号 12, p. 327-341, 発行日 1971-10 |
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| 抄録（英） | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | The rotational transitions in molecular collisions in the para-hydrogen gas are theoretically studied in the distorted-wave approximation. In the long-range part of the intermolecular force, the orientation-dependence of the dipole-dipole dispersion force and the quadrupole-quadrupole interaction are fully taken into account. In the short-range part of the interaction, the anisotropy parameter is determined empirically in such a way as the calculated rate constants explain the ultrasonic absorption data at 90°K. It is shown that our rotational cross sections can explain satisfactorily the ultrasonic absorption experiment at 90° and 293°K, but the agreement with the ultrasonic dispersion experiment is less satisfactory. The orientation-dependence of the long-range interactions and the simultaneous transitions in two colliding molecules are both found important. Furthermore, it is found that the cross sections are large when the collision partner is in an excited state of rotation. | |||||||||
| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 0372-1418 | |||||||||
| 書誌レコードID | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| 収録物識別子 | AA00675986 | |||||||||
| 資料番号 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | 資料番号: SA2400827000 | |||||||||
