{"_buckets": {"deposit": "50cc1ea3-8f63-4abc-8cbd-c89ec71051f0"}, "_deposit": {"created_by": 1, "id": "1938", "owners": [1], "pid": {"revision_id": 0, "type": "depid", "value": "1938"}, "status": "published"}, "_oai": {"id": "oai:jaxa.repo.nii.ac.jp:00001938", "sets": ["70", "1426", "1893"]}, "author_link": ["1621", "1617", "1614", "1619", "1618", "1615", "1616", "1609", "1611", "1608", "1620", "1610", "1613", "1612"], "item_3_alternative_title_2": {"attribute_name": "その他のタイトル（英）", "attribute_value_mlt": [{"subitem_alternative_title": "Thermal and combustion characteristics of 1,2,4-triazole-3-one copper complex nitrate"}]}, "item_3_biblio_info_10": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2015-03-13", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "39", "bibliographicPageStart": "33", "bibliographicVolumeNumber": "JAXA-RR-14-005", "bibliographic_titles": [{"bibliographic_title": "宇宙航空研究開発機構研究開発報告: 高エネルギー物質研究会: 平成26年度研究成果報告書"}, {"bibliographic_title": "JAXA Research and Development Report", "bibliographic_titleLang": "en"}]}]}, "item_3_description_16": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "本研究の目的は，ガス発生剤として1,2,4-トリアゾール-3-オン銅錯体硝酸塩(TOCu)を合成し，熱的特性および初期分解機構の検討からTOCuの反応性に及ぼすCuの影響を検討することである．ガス発生剤としての性能評価は燃焼試験により行った．TOCuは，1,2,4-トリアゾール-3-オン(TO)および硝酸銅(Ⅱ)･3水和物(Cu(NO3)2・3H2O)を用いて合成した．元素分析の結果からTOCuは，Cu2+-bis[(C2H3N3O)(NO3)(-)]･2H2Oとして合成された． TOCuの熱的特性を検討し，発熱量および発熱ピークの鋭さからTOおよびTO/Cu(NO3)2・3H2Oのそれらより反応性が向上されたことがわかった．生成ガス分析からTOCuは，N2，H2O， HNCO， HCN，CO2，CO，NOx ，NH3のガスが生成されることがわかった．TOCuの燃焼特性の検討し，Vieille\u0027s の式に従い圧力指数を算出し，0.6451であることがわかった．", "subitem_description_type": "Abstract"}]}, "item_3_description_17": {"attribute_name": "抄録（英）", "attribute_value_mlt": [{"subitem_description": "In order to obtain a better understanding of the thermal characteristics and combustion characteristics of 1,2,4-triazole-3-one copper complex (TOCu), elemental analysis, infrared spectrometry (IR), X-ray diffraction(XRD), sealed cell-differential scanning calorimetry (SC-DSC), themogravimetry-differential thermal analysis-mass spectrometry (TG-DTA-MS) and burning test were performed. TOCu was synthesized from 1,2,4-triazole-3-one (TO) and trihydrated copper nitrate (Cu(NO3)2･3H2O). TOCu was obtained as 〔Cu(2+)(C2N3H3O)2(NO3)(-)2・2H2O〕. From the DSC results, the heat of reaction of TOCu was larger than those of pure TO and TO/Cu(NO3)2･3H2O mixtures. The exothermic peak of TOCu sharply became compared with those of pure TO and TO/Cu(NO3)2･3H2O mixtures. It was found that the reactivity of TOCu was improved to compared with those of pure TO and TO/Cu(NO3)2･3H2O mixtures. TG-DTA-MS curves of TOCu were showed from 3 steps of mass loss, exothermic peak and decomposition gases in the temperature ranges were 100-180 C, 200-260 C and 300-360 C. From the results of TG-DTA-MS, the gases evolved from TOCu were determined as N2, H2O, HNCO, HCN, CO2, CO, NOx and NH3 at 100-360 C. From burning test results, the burning rate of TOCu was calculated by pressure exponent 0.6451 based on Vieille\u0027s law.", "subitem_description_type": "Other"}]}, "item_3_description_18": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "形態: カラー図版あり", "subitem_description_type": "Other"}]}, "item_3_description_19": {"attribute_name": "内容記述（英）", "attribute_value_mlt": [{"subitem_description": "Physical characteristics: Original contains color illustrations", "subitem_description_type": "Other"}]}, "item_3_description_32": {"attribute_name": "資料番号", "attribute_value_mlt": [{"subitem_description": "資料番号: AA1530013005", "subitem_description_type": "Other"}]}, "item_3_description_33": {"attribute_name": "レポート番号", "attribute_value_mlt": [{"subitem_description": "レポート番号: JAXA-RR-14-005", "subitem_description_type": "Other"}]}, "item_3_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "宇宙航空研究開発機構(JAXA)"}]}, "item_3_publisher_9": 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[{"subitem_text_value": "NASA分類: Propellants and Fuels"}]}, "item_3_text_40": {"attribute_name": "jaxa出版物種類", "attribute_value_mlt": [{"subitem_text_value": "jaxa出版物種類: RR"}]}, "item_3_text_41": {"attribute_name": "jaxa出版物シリーズ", "attribute_value_mlt": [{"subitem_text_value": "jaxa出版物シリーズ: 003"}]}, "item_3_text_43": {"attribute_name": "DSpaceコレクション番号", "attribute_value_mlt": [{"subitem_text_value": "DSpaceコレクション番号: 10"}]}, "item_3_text_6": {"attribute_name": "著者所属", "attribute_value_mlt": [{"subitem_text_value": "日本大学"}, {"subitem_text_value": "日本大学"}, {"subitem_text_value": "横浜国立大学"}, {"subitem_text_value": "株式会社ダイセル"}, {"subitem_text_value": "宇宙航空研究開発機構宇宙科学研究所宇宙飛翔工学研究系(JAXA)(ISAS)"}, {"subitem_text_value": "日本大学"}, {"subitem_text_value": "日本大学"}]}, "item_3_text_7": {"attribute_name": "著者所属（英）", "attribute_value_mlt": [{"subitem_text_language": "en", "subitem_text_value": "Nihon University"}, {"subitem_text_language": "en", "subitem_text_value": "Nihon University"}, {"subitem_text_language": "en", "subitem_text_value": "Yokohama National University"}, {"subitem_text_language": "en", "subitem_text_value": "Daicel Corporation"}, {"subitem_text_language": "en", "subitem_text_value": "Department of Space Flight Systems, Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency (JAXA)(ISAS)"}, {"subitem_text_language": "en", "subitem_text_value": "Nihon University"}, {"subitem_text_language": "en", "subitem_text_value": "Nihon University"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "大貫, 学"}], "nameIdentifiers": [{"nameIdentifier": "1608", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "吉野, 悟"}], "nameIdentifiers": [{"nameIdentifier": "1609", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "三宅, 淳巳"}], "nameIdentifiers": [{"nameIdentifier": "1610", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": 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